Synthesis of Water-Soluble Iridium (III)-Containing Nanoparticles for Biological Applications
نویسندگان
چکیده
منابع مشابه
A water-soluble iridium(III) porphyrin.
This work reports the synthesis and characterization of the first water-soluble iridium porphyrin, iridium(iii) diaqua porphyrin [Ir(III)(TSPP)(OH(2))(2)](3-) (1, TSPP = tetra-p-sulfonatophenyl porphyrin). The structure of 1 was unequivocally determined by single crystal X-ray analysis. Benzo-18-crown-6-ether is essential for producing single crystals suitable for X-ray analysis.
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The chemiluminescence from four cyclometalated iridium(III) complexes containing an ancillary bathophenanthroline-disulfonate ligand exhibited a wide range of emission colours (green to red), and in some cases intensities that are far greater than the commonly employed benchmark reagent, [Ru(bpy)3](2+). A similar complex incorporating a sulfonated triazolylpyridine-based ligand enabled the emis...
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We report an ecofriendly novel method for copper nanoparticles (CuNPs) synthesis by hydrothermal processes using an activated carboxymethyl gum of locally available medicinal plant Cochlospermum gossypiumas capping agent. The synthesized CuNPs characterized by Ultraviolet - visible Spectroscopy (UV-Vis), Fourier – transform infrared Spectroscopy (FTIR), and Transmission Electron Micros...
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Aminocarboxylic acids, such as 2-aminobenzoic acid, react easily with [Ir(COD)(PMe3)3]Cl, (COD=1,5-cyclooctadiene), in THF to produce hydridoaminocarboxylato iridium(III) complexes in high yields. These octahedral complexes are formed via oxidative addition reaction of the O-H bond of the carboxylic group with the central metal. The starting iridium(I) complex losses t...
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ژورنال
عنوان ژورنال: Journal of Chemistry
سال: 2015
ISSN: 2090-9063,2090-9071
DOI: 10.1155/2015/475602